A process for the preparation of epoxy(meth)acrylates

C - Chemistry – Metallurgy – 08 – G

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Details

C08G 59/16 (2006.01) C08F 20/32 (2006.01) C08G 59/42 (2006.01) C08L 63/10 (2006.01)

Patent

CA 2208301

The present invention relates to a process for the preparation of epoxy(meth)acrylates by simultaneously reacting 1 equivalent of organic compounds containing epoxide groups with A) 0.8 to 1.2 moles of organic dicarboxylic anhydrides having a molecular weight from 98 to 166 and B) 0.8 to 1.2 OH equivalents of OH group-containing reaction products, which are prepared at a COOH/OH equivalent ratio of 0.6:1 to 0.95:1, of a) (meth)acrylic acid and b) tri- or tetrahydric ether alcohols having a molecular weight of 180 to 1000 and containing at least two ethylene and/or propylene oxide units as part of an ether structure.

La présente invention représente un procédé pour la préparation d'époxy(méth)acrylates en faisant réagir, simultanément, 1 équivalent de composés organiques contenant des groupes d'époxydes avec A) de 0,8 à 1,2 mols d'anhydrides dicarboxyliques organiques dont la masse moléculaire varie entre 98 et 166, et B) de 0,8 à 1,2 d'équivalents de OH de produits de réaction ayant des groupes contenant du OH, préparés à un rapport équivalent COOH/OH de 0,6:1 à 0,95:1, d'un a) acide (méth)acrylique et b) d'éther d'alcools tri- ou tétrahydriques dont la masse moléculaire varie entre 180 à 1000 et qui contient au moins deux unités d'oxyde d'éthylène et (ou) de propylène dans une structure d'éther.

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