A process for the production of an olefin oxide, a 1,2-diol,...

C - Chemistry – Metallurgy – 07 – D

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C07D 301/10 (2006.01)

Patent

CA 2685703

A process for the epoxidation of an olefin comprising contacting a reactor feed comprising an olefin, oxygen, and carbon dioxide, with a catalyst comprising a carrier and, deposited on the carrier, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the carbon dioxide is present in the reactor feed in a quantity of at most 3 mole percent based on the total epoxidation reactor feed; the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; and the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof; a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.

L'invention concerne un procédé d'époxydation d'une oléfine qui consiste à mettre en contact une charge de réacteur contenant une oléfine, de l'oxygène et du dioxyde de carbone, avec un catalyseur contenant un support et, déposé sur le support, de l'argent, un promoteur de rhénium, un premier co-promoteur et un second co-promoteur; le dioxyde de carbone est présent dans la charge du réacteur en quantité équivalente à au moins 3 mole pourcent sur la base de la charge totale du réacteur d'époxydation; le premier co-promoteur est sélectionné parmi le soufre, le phosphore, le bore et des mélanges de ceux-ci; et le second promoteur est sélectionné parmi le tungstène, le molybdène, le chrome et des mélanges de ceux-ci; un procédé de préparation d'un 1,2-diol, d'un éther de 1,2-diol, d'un 1,2-carbonate ou d'une alcanolamine.

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