A process for the synthesis of alkoxyamines and their use in...

C - Chemistry – Metallurgy – 07 – D

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C07D 211/94 (2006.01) C07D 295/24 (2006.01) C08F 2/38 (2006.01) C08F 4/00 (2006.01)

Patent

CA 2432910

A one-pot process for the preparation of alkoxyamines conforming to formulae (I) or (II), preferably (I) (See formulas I and II) is disclosed. The process entails (1) reacting of an oxidizing agent (A) with a sterically hindered secondary amine of the general formula (III), (See formula III) in a water-containing medium to form a reaction product and an aqueous phase, (2) removing of the aqueous phase, and (3) adding to the reaction product a free-radical initiator (B) under conditions that promote the decomposition of the initiator to generate free radicals. Also disclosed is a process for polymerizing monomers, the process using the alkoxyamine prepared by the inventive process.

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