C - Chemistry – Metallurgy – 07 – D
Patent
C - Chemistry, Metallurgy
07
D
C07D 211/94 (2006.01) C07D 295/24 (2006.01) C08F 2/38 (2006.01) C08F 4/00 (2006.01)
Patent
CA 2432910
A one-pot process for the preparation of alkoxyamines conforming to formulae (I) or (II), preferably (I) (See formulas I and II) is disclosed. The process entails (1) reacting of an oxidizing agent (A) with a sterically hindered secondary amine of the general formula (III), (See formula III) in a water-containing medium to form a reaction product and an aqueous phase, (2) removing of the aqueous phase, and (3) adding to the reaction product a free-radical initiator (B) under conditions that promote the decomposition of the initiator to generate free radicals. Also disclosed is a process for polymerizing monomers, the process using the alkoxyamine prepared by the inventive process.
Detrembleur Christophe
Gross Thomas
Meyer Rolf-Volker
Aktiengesellschaft Bayer
Ogilvy Renault Llp/s.e.n.c.r.l.,s.r.l.
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