A reference electrode solution containing organic ammonium...

G - Physics – 01 – N

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G01N 27/30 (2006.01)

Patent

CA 2353641

The present invention provides a reference electrode solution containing ammonium salts and phosphonium salts for the potentiometric measurement of pH and method of using the same. The use of the ammonium salts and the phosphonium salts to replace potassium chloride or sodium chloride as reference electrolytes in a standard reference electrode minimizes the formation of precipitates in sample solutions containing cation-sensitive compounds. Disruption of ion flow through the reference electrode is eliminated, and accurate pH measurements may be obtained in solutions that contain compounds having a strong affinity for hard cations.

L'invention concerne une solution d'électrodes de référence contenant des sels organiques d'ammonium et de phosphonium destinée à la mesure potentiométrique du pH et un procédé d'utilisation correspondant. L'utilisation de sels d'ammonium et de phosphonium au lieu des chlorures de potassium ou de sodium, utilisés comme électrolytes de référence avec une électrode de référence standard, réduit au minimum la formation de précipités dans des solutions d'échantillon contenant des composés sensibles aux cations. On parvient à éliminer l'interruption du flux d'ions à travers l'électrode de référence et à mesure le pH avec précision dans des solutions contenant des composés qui possèdent une forte affinité pour les cations durs.

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