Acetic acid from ethylene

B - Operations – Transporting – 01 – J

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B01J 21/06 (2006.01) B01J 23/38 (2006.01) B01J 27/18 (2006.01) C07C 51/25 (2006.01) C07C 53/08 (2006.01)

Patent

CA 2055836

CSL-P-4191 ABSTRACT OF THE DISCLOSURE Disclosed is making acetic acid by reacting in a reaction zone ethylene and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcox (formula 1) where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein such catalyst contains crystalline TiP207. Applns.AZ9 -13-

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