Acid copper electroplating baths containing brightening and...

C - Chemistry – Metallurgy – 25 – D

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204/36

C25D 3/38 (2006.01)

Patent

CA 1194832

ABSTRACT OF THE DISCLOSURE The invention is concerned with the electrodeposition of copper from an aqueous acidic bath containing the following additives: a. An alkylated polyalkyleneimine obtained as the reaction product of a polyalkyleneimine represented by the formula: H2N-(CH2)n-NH-R wherein R is H or (CH2)n NH2 and n = 1 to 6 with an epihalohydrin and an alkylat- ing agent; and optionally an organic sulfo sulfonate; a polyether; and/or a thio- organic compound. The novel aqueous acidic copper baths provide bright and leveled copper electrodeposits over a wide current density range including low current densities on the order of 0.4 amps. sq. dm. or less with strong leveling properties throughout.

403086

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