Acyclic anionic six-electron-donor ancillary ligands

C - Chemistry – Metallurgy – 07 – F

Patent

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Details

C07F 5/02 (2006.01) C07F 5/06 (2006.01) C07F 7/00 (2006.01) C07F 7/28 (2006.01) C07F 17/00 (2006.01) C08F 4/00 (2006.01) C08F 10/00 (2006.01)

Patent

CA 2474041

The present invention provides an improved acyclic anionic six-electron-donor ancillary ligand suitable for being bonded in a transition metal complex. The present invention also provides a transition metal complex that includes at least one acyclic anionic six-electron-donor ancillary ligand which is suitable for use as an olefin polymerization catalyst. The complex includes a Group 3 to 10 transition or lanthanide metal and one or more anionic or neutral ligands in an amount that satisfies the valency of the metal such that the complex has a net zero charge. The present invention also discloses a method for making transition metal complex and a method for using the complex for olefin polymerization.

Cette invention se rapporte à un ligand auxiliaire anionique acyclique amélioré avec donneur de six électrons conçus pour subir une liaison dans un complexe de métaux de transition. Cette invention concerne également un complexe de métaux de transition qui contient au moins un ligand auxiliaire anionique acyclique avec donneur de six électrons pouvant être utilisé comme catalyseur de polymérisation d'oléfines. Ce complexe contient un métal de transition des groupes 3 à 10 ou un métal lanthanide et un ou plusieurs ligands anioniques ou neutres en une quantité apte à satisfaire la balance du métal, pour que ledit complexe possède une charge nette égale à 0. Cette invention concerne également un procédé servant à produire un complexe de métaux de transition et un procédé destiné à utiliser ce complexe pour la polymérisation d'oléfines.

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