Adhesives and method for making same

C - Chemistry – Metallurgy – 08 – G

Patent

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Details

C08G 71/04 (2006.01) C08G 18/32 (2006.01) C08G 59/50 (2006.01) C09J 175/12 (2006.01)

Patent

CA 2055467

2055467 9100308 PCTABS00003 A thermosetting mixture for use as an adhesive, as well as other applications, that is substantially nonmutagenic. This mixture is based upon a thermosetting resin selected from polyurethane and epoxy resins, using an improved curing agent that does not contain mutagenic components. Specifically, the curing agent is a multi-mixture of substituted alkylanilines produced by an improved process. These alkylanilines are formed by condensation of at least two alkylanilines with a formaldehyde in an acid solution. Upon purification, at least three aromatic diamines are formed that are used for the curing agent with the polyurethane and epoxy resins. Pot life, green strength and ultimate strength are comparable to adhesives of the prior art that contain mutagenic constituents. Although several dialines are described, the preferred curing agents are formed using 2,6-diethylaniline (DEA) and 2,6-diisopropylaniline (DIPA), where the mole % of DEA and DIPA is 38-48 and 62-52, respectively. Curing agents within the preferred range have been designated as "Asilamine 4852" and "Asilamine 4555".

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