Aging of chromium-containing gel at high ph

C - Chemistry – Metallurgy – 08 – F

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252/104, 402/631

C08F 4/22 (2006.01) C08F 4/74 (2006.01) C08F 10/00 (2006.01)

Patent

CA 1190538

Abstract of the Disclosure A silica hydrogel containing chromium is aged under conditions such that at least a portion of the aging is carried out at a pH within the range of 7 to 9. The resulting hydrogel is converted to a xerogel by treating with a volatile organic liquid. The desired pH can be obtained either by adding a basic material such as ammonia to the hydro- gel prior to or during the aging process or by using a chromium component which inherently gives a higher pH and/or resists the natural tendency for the pH to decrease during aging. An example of such a chromium com- pound is chloropentammine chromium(III)chloride. The resulting catalyst on activation is particularly suitable for olefin polymerization under conditions where higher melt flow polymer is desired.

418967

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