Air-drying aqueous polymer dispersions

C - Chemistry – Metallurgy – 08 – L

Patent

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Details

C08L 51/08 (2006.01) C08F 8/14 (2006.01) C08F 8/44 (2006.01) C09D 151/08 (2006.01)

Patent

CA 2113753

AIR-DRYING AQUEOUS POLYMER DISPERSIONS ABSTRACT OF THE DISCLOSURE The invention relates to an air-drying aqueous polymer dispersion based on a core/shell polymer having an alkyd resin in the core and an addition polymer grafted thereon, with 50-90 weight percent of the core/shell polymer being composed of alkyd resin and 50-10 weight percent being composed of addition polymer, and with the alkyd resin - containing more than 40 and up to 80 weight percent of unsaturated fatty acid, at least 5 mole percent of which contains conjugated double bonds, - having an acid number of not more than 5 (mg KOH/g), and - having a number average molecular weight in the range of 400 to 5000, and with the addition polymer having an acid number in the range of 40 to 200 (mg KOH/g). The aqueous polymer dispersions according to the invention were found to be highly stable and to have a comparatively low viscosity, even at concentrations of 40 weight percent and above. It was found that topcoats obtained using dispersions with a high alkyd resin content are virtually identical in terms of properties with topcoats obtained in a traditional manner using alkyd paints based on organic solvents, while the gloss of topcoats obtained using the polymer dispersions according to the invention frequently is even higher.

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