Aldehyde and process for producing the same

C - Chemistry – Metallurgy – 07 – C

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C07C 61/22 (2006.01) B01J 31/24 (2006.01) B01J 31/28 (2006.01) C07C 51/373 (2006.01) C07C 62/16 (2006.01) C07C 69/757 (2006.01) C07D 307/89 (2006.01)

Patent

CA 1234127

ABSTRACT OF THE DISCLOSURE A novel aldehyde, 4-formylcyclohexane-1,2-dicarboxylic acid, is prepared by the reaction of 4-cyclohexene-1,2-dicarboxylic acid with hydrogen and carbon monoxide in the presence of a hydroformylation catalyst. Products in which hydrogen of the ring is substituted by other groups, and derivatives of the carboxyl groups, may also be prepared. Useful catalysts include rhodium carbonyl complex compounds with tertiary phosphine ligands with excess of the tertiary phosphine ligands. The new aldehydes of this invention are useful as intermediates for hexahydrotrimellitic acid and derivatives thereof and trimellitic acid and derivatives thereof which are useful as plasticizer or raw material of heat resistant plastic.

417341

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