Aldol condensations by catalytic antibodies

Details Aldol condensations by catalytic antibodies Aldol condensations by catalytic antibodies

C - Chemistry, Metallurgy

12

P

C12P 7/26 (2006.01) C12N 9/00 (2006.01)

Patent

CA 2315260

Catalytic antibodies, including 38C2 and 33F12, are capable of efficiently catalyzing a wide variety of ketone-ketone, ketone-aldehyde, aldehyde-ketone, and aldehyde-aldehyde intermolecular aldol reactions, and in some cases to catalyze their subsequent dehydration to yield aldol condensation products. A number of intramolecular aldol reactions have also been defined. Catalysis of all intramolecular aldol reactions examined yields the corresponding condensation products.

Cette invention concerne des anticorps catalytiques, comprenant 38C2 et 33F12, qui sont capables de catalyser efficacement une grande diversité de réactions aldol intermoléculaires cétone-cétone, cétone-aldéhyde, aldéhyde-cétone, et aldéhyde-aldéhyde, et dans certains cas de catalyser la déshydratation subséquente pour produire des produits de condensation aldol. On a également défini un certain nombre de réactions aldol intramoléculaires. La catalyse de toutes les réactions aldol intramoléculaires examinées a eu pour résultat les produits de condensation correspondants.

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