Alkylation inhibitors for a ligand-complexing process

C - Chemistry – Metallurgy – 07 – C

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260/719.5

C07C 11/02 (2006.01) B01D 53/14 (2006.01) C07C 7/152 (2006.01)

Patent

CA 1140946

Abstract of the Disclosure In processes in which liquid sorbents that are solutions in an aromatic hydrocarbon or halogenated aromatic hydrocarbon of a bimetallic salt complex having the generic formula MIMIIXn?Aromatic, wherein MI is a Group I-B metal, MII is a Group III-A metal, X is halogen, n is the sum of the valences of MI and MII, and Aromatic is a monocyclic aromatic hydrocarbon or halogenated aromatic hydrocarbon are used to separate complexible ligands from a gas feedstream that com- prises an olefin having 2 or 3 carbon atoms, alkylation of the aromatic hydrocarbon or halogenated aromatic hydrocarbon is inhibited by incorporating in the liquid sorbent a small amount of an alkylation inhibitor that is zinc diphenyl or triphenylboron.

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