Alkylation of halodisilanes

C - Chemistry – Metallurgy – 07 – F

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260/448

C07F 7/12 (2006.01) C07F 7/08 (2006.01)

Patent

CA 1339318

A process for the preparation of more highly alkylated silanes and disilanes. The process comprises (A) contacting a halodisilane, with an alkyl halide in the presence of a metal, such as aluminum, which serves as a halogen acceptor, (B) reacting the halodisilane with the alkyl halide in the presence of the metal at a temperature greater than about 150°C. to form the more highly alkylated silanes and disilanes and a metal halide; and (C) isolating and separating the more highly alkylated silanes and disilanes.

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