Allylic oxidation of olefins

Details Allylic oxidation of olefins Allylic oxidation of olefins

C - Chemistry, Metallurgy

07

C

C07C 35/18 (2006.01) C07C 29/40 (2006.01) C07C 29/50 (2006.01) C07C 33/03 (2006.01) C07C 45/34 (2006.01) C07C 45/35 (2006.01) C07C 47/21 (2006.01) C07C 49/203 (2006.01) C07C 49/603 (2006.01) C07C 51/25 (2006.01) C07C 57/03 (2006.01)

Patent

CA 2074880

ABSTRACT Allylic oxidation of olefins such as propylene or cyclohexene is performed with oxygen-containing gas and a metal, preferably iron, porphyrin ligand containing electron-withdrawing substituents such as halide, preferably fluoride, nitro or cyano substituted for hydrogen in the ligand. a:olefin2

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