Allylic rearrangement process

C - Chemistry – Metallurgy – 07 – C

Patent

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260/631.7

C07C 33/02 (2006.01) C07C 29/09 (2006.01) C07C 29/12 (2006.01) C07C 29/56 (2006.01) C07C 29/70 (2006.01)

Patent

CA 1118793

ABSTRACT A process for allylic rearrangement, particularly terpenoid allylic rearrangement, utilizing certain acid forming metals to form an estel or alcoholate (alcohologen) of the allylic alcohol to be rearranged, isomerizing and cleaving the alcohologen in the presence of a transition metal compound catalyst and recovering the rearranged alcohol.

341146

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