Allylic side chain-containing solid phase systems, processes...

Details Allylic side chain-containing solid phase systems, processes... Allylic side chain-containing solid phase systems, processes...

C - Chemistry, Metallurgy

07

K

260/229, 402/399

C07K 1/04 (2006.01) C07H 19/04 (2006.01) C07K 9/00 (2006.01) C07K 17/08 (2006.01)

Patent

CA 1315470

ABSTRACT Allylic side chain-containing solid phase systems, processes for the preparation thereof and the use thereof in solid phase reactions The present invention provides an allylic side chain-containing solid phase system, in which the allylic side chains are bound to a solid carrier material, of the general formula Image (I) wherein F is a solid carrier material, R1 and R2, which can be the same or different, are hydrogen or halogen atoms or alkyl or aryl radicals, R3 is a linking group- ing (spacer), X is a hydroxyl group, a halogen atom, a sulphonate or phosphonate group or an acyloxy radical, acyl in the acyloxy radical being the residue of an aliphatic carboxylic acid or the radical RCO-, R being an organic radical, which is bound via the carbonyl group, and n is the number of side chains bound to the carrier material. The present invention also provides processes for the preparation of these solid phase systems and is also concerned with the use thereof for solid phase reactions.

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