.alpha.,.beta.-unsaturated carbonyl-functional silicone...

C - Chemistry – Metallurgy – 08 – G

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402/12, 402/17,

C08G 77/392 (2006.01) C08F 30/08 (2006.01) C08F 283/12 (2006.01) C08F 290/06 (2006.01) C08L 83/08 (2006.01)

Patent

CA 1326041

.alpha.,.beta. -UNSATURATED CARBONYL-FUNCTIONAL SILICONE COMPOSITIONS Abstract of the Disclosure Polymerizable .alpha. , .beta.-unsaturated carbonyl-functional silicone compositions are obtained from the reaction of thiol- functional organopolysiloxanes with an .alpha. ,.beta. -unsaturated car- bonyl-functional compound having at least two acryloyl or methacryloyl groups or mixtures thereof per molecule in the presence of a base catalyst. The .alpha., .beta.-unsaturated carbonyl-functional silicone compositions may be combined with a photosensitizer and/or a free radical generator and polymerized by radiation and/or heat.

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