Alpha halo substituted asymmetrical diacyl peroxides in...

C - Chemistry – Metallurgy – 08 – F

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252/122, 402/508

C08F 4/38 (2006.01) C08F 14/06 (2006.01) C08F 214/06 (2006.01)

Patent

CA 1097607

ABSTRACT OF THE DISCLOSURE Organic peroxide polymerization co-initiator compo- sitions and their use in the initiation of the polymeri- zation of certain monomers and comonomers such as vinyl chloride, ethylene and methyl methacrylate. The co-initiator composition contains an alpha halo substituted diacyl peroxide and a coperoxide selected from t-alkyl peresters of t-hydroperoxides, peroxydicarbonates, acyl peroxycarbonic esters, and aliphatic diacyl peroxides. Typical is acetyl 2-chlorooctanoyl peroxide with t-butyl peroxy neodecanoate.

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