Alpha-olefin polymerization catalysts comprising supported...

C - Chemistry – Metallurgy – 08 – F

Patent

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C08F 4/78 (2006.01) C08F 4/69 (2006.01) C08F 10/00 (2006.01) C08F 4/639 (2006.01) C08F 4/6392 (2006.01)

Patent

CA 2127447

Disclosed is a catalyst system for the homopolymerization and copolymerization of alpha-olefins having 2-8 carbon atoms, said catalyst system comprising a cyclopentadienyl Group 6b metal compound having at least one oxo, thio, imido or phosphido group bonded directly to the Group 6b metal, and at least one organic radical bonded to the Group 6b metal through a carbon atom, said Group 6b metal compound being supported on an inorganic support. The catalyst system may also contain a Group 2 or Group 3 metal alkyl compound cocatalyst.

L'invention concerne un système catalyseur utilisé pour l'homopolymérisation et la copolymérisation d'alpha-oléfines ayant 2 à 8 atomes de carbone, ledit système catalyseur comprenant un composé cyclopentadiényle d'un métal du groupe 6b et contenant au moins un groupe oxo, thio, imido ou phosphido lié directement au métal du groupe 6b, et au moins un radical organique lié au métal du groupe 6b par l'intermédiaire d'un atome de carbone, ledit composé de métal du groupe 6b étant soutenu par un support inorganique. Le système catalyseur peut également contenir un cocatalyseur qui est un composé alkyle d'un métal du groupe 2 ou du groupe 3.

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