Alternating (aba)n polylactide block copolymers

C - Chemistry – Metallurgy – 08 – G

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C08G 18/42 (2006.01) C08G 18/61 (2006.01) C08G 63/08 (2006.01)

Patent

CA 2155678

Polymers of the general formula R(A-B-A-L)?A-B-A-R and their preparation are disclosed. In the general formula, -A- is a polyhydroxy acid residue preferably a polymer of either 98 to 100 % L-lactide or 98 to 100% D-lactide having a molecular weight of 500 to 40,000 and preferably 2,000 to 20,000, -B- is an oligomeric diol or diamine residue, having a number average molecular weight of 500 to 20,000 and preferably 2,000 to 8,000. The polymers are prepared by polymerizing a lactone onto the diol or diamine followed by reacting the resulting polymeric H-A-B-A-H with a diisocyanate or diacyl chloride to form the -L- chain extending units in the general formula.

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