Amino or thiol linker building block for the synthesis of...

C - Chemistry – Metallurgy – 07 – F

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C07F 9/06 (2006.01) C07F 17/02 (2006.01) C07H 21/00 (2006.01)

Patent

CA 2584799

An amino or thiol linker building block for the synthesis of amino or thiol functionalized amino acids and generally of the following structure: Formula XII is provided. Such building block may be introduced in the 5' end position of an amino acid under standard coupling conditions. Such building block allows in~line coupling control, "trityl-on" purification, and solid support functionalization/derivatization. Such building block is a stable, solid compound and can therefore be easily handled. With the building block of the present invention, deprotection may be carried out under standard detritylation conditions.

Un bloc de construction de liants amino ou thiol pour la synthèse d'acides aminés fonctionnalisés amino ou thiol ayant normalement la structure suivante: formule XII. Un tel bloc peut être introduit dans la position de terminaison 5' d'un acide aminé dans des conditions de couplage standard. Il permet de surveiller le couplage en ligne, d'assurer une purification "trityl-on" et d'assurer une fonctionnalisation/dérivatisation d'un support solide. Ce bloc est un composé stable et solide d'où une manipulation aisée. Grâce à ce bloc, on peut effectuer une déprotection dans des conditions de détritylation standard.

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