An aqueous dispersion of polyurethane resins, a method of...

C - Chemistry – Metallurgy – 08 – L

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C08L 75/04 (2006.01) B05D 1/36 (2006.01) C08G 18/08 (2006.01) C08G 18/10 (2006.01) C08G 18/12 (2006.01) C08G 18/66 (2006.01) C08G 18/80 (2006.01) C09D 175/04 (2006.01) C09D 175/06 (2006.01)

Patent

CA 2127761

An aqueous dispersion of polyurethane resins free from urea groups and containing ionic groups and with a number average molecular weight (Mn) of 10 000 to 300 000 and an acid number of 5 to 50, and a method of manufacturing them by preparing a polyurethane prepolymer containing OH groups and with an OH number of 5 to 75 and a number average molecular weight (Mn) of 5 000 to 50 000, by reacting the following in an organic medium: A) one or more compounds which react with isocyanate and have an acid number of 0 to 10; B) one or more substances containing free isocyanate groups; C) one or more polyisocyanates with at least two free isocyanate groups per molecule, in a proportion such that the molar ratio of the OH groups in component A) to the NCO groups in components B) and C) is 1.01 : 1 to 3 : 1, after which the prepolymer obtained from A), B) and C), before or after partial or complete neutralisation of any groups present which are convertible into ionic groups, is subjected to a chain-lengthening process in the organic medium or after conversion to the aqueous phase, by reaction with D) one or more polyfunctional isocyanates with a functionality of free NCO groups of at least 1.8, in proportions such that the final polyurethane resin has the desired number average molecular weight.

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