An electrolytic process for the generation of stable...

C - Chemistry – Metallurgy – 25 – B

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C25B 1/26 (2006.01) C25B 1/24 (2006.01)

Patent

CA 2429908

Chlorine dioxide gas dissolved in water is produced by passing a solution of stabilized chlorine dioxide or a sodium chlorite solution, with or without added sodium chloride, through an electrolytic cell having an anode and cathode, in the absence of a semi-permeable membrane but in the presence of a buffer. An anolyte with a pH below 10 is produced so that disproportination of the ClO2 in not appreciable.

Selon l'invention, du gaz de dioxyde de chlore dissous dans de l'eau est produit par le passage d'une solution de dioxyde de chlore stabilisé ou d'une solution de chlorite de sodium, avec ou sans chlorure de sodium ajouté, à travers une cellule d'électrolyse comportant une anode et une cathode. En l'absence d'une membrane semi-perméable mais en la présence d'un tampon, un anolyte comprenant un pH inférieur à 10 est produit de sorte que la dismutation du ClO¿2? ne soit pas appréciable.

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