Anthracyclines

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C - Chemistry, Metallurgy

07

H

260/208.1

C07H 15/24 (2006.01)

Patent

CA 1095028

ABSTRACT OF THE DISCLOSURE This invention discloses a process for producing 9-desacetyl-9-keto-N-trifluoroacetyl-daunorubicin and the compound itself. The process comprises oxidizing N-trifluoro- acetyl-13-dihydrodaunorubicin in t-butyl alcohol in the presence of two equivalents of sodium periodate. These compounds are unexpectedly stable intermediates useful in the production of new daunorubicin derivatives which are used in treating certain mammalian tumours.

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