Anti-oxidant macromonomers and polymers and methods of...

C - Chemistry – Metallurgy – 09 – K

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C09K 15/08 (2006.01) C07C 37/00 (2006.01) C08G 61/02 (2006.01)

Patent

CA 2574588

The present invention relates to macromonomer compounds possessing antioxidant properties, antioxidant polymers comprising the antioxidant macromonomers as a recurring unit, and methods of inhibiting oxidation in a substance comprising contacting the substance with the antioxidant polymers. In one embodiment, substantially all of the recurring macromonomeric units of the antioxidant polymers comprise an antioxidant moiety. In another embodiment, all of the recurring macromonomer units of the antioxidant polymers comprise an antioxidant moiety. The method of the present invention, yields antioxidant polymers with substantially all of the recurring units comprising an antioxidant moiety. These antioxidant polymers have greater bulk antioxidative properties than previously known.

L'invention concerne des composés macromonomères présentant des propriétés antioxydantes, des polymères antioxydants comprenant ces macromonomères antioxydants ainsi qu'un motif récurrent, et des procédés pour inhiber l'oxydation d'une substance, consistant à mettre cette substance en contact avec lesdits polymères antioxydants. Dans un mode de réalisation, sensiblement tous les motifs macromonomères récurrents des polymères antioxydants comportent une fraction antioxydante. Dans un autre mode de réalisation, tous les motifs macromonomères récurrents des polymères antioxydants comportent une fraction antioxydante. Les procédés selon l'invention permettent de produire des polymères antioxydants renfermant sensiblement tous les motifs récurrents qui comportent une fraction antioxydante. Les polymères antioxydants selon l'invention présentent des propriétés antioxydantes globales plus grandes que les polymères antioxydants selon l'art antérieur.

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