Antiwear agents for lubricating compositions

C - Chemistry – Metallurgy – 10 – M

Patent

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Details

C10M 139/00 (2006.01) C07F 5/02 (2006.01) C07F 5/04 (2006.01) C07F 5/05 (2006.01)

Patent

CA 2281606

Sulfur-containing boroester compounds useful as antiwear additives for oleaginous compositions including acyclic borate thioesters having general formula (I) wherein R1 represents a hydrocarbyl radical having between 4 to 12 carbon atoms, R2 and R3 independently represent -(OR4)nSR1 and -(OR4)nSR1OH; R4 represents a hydrocarbyl radical having between 1 to 6 carbon atoms; n is an integer of from between 1 to 4; and 1 and m are independently 0, 1 or 2; or thioalkyl-substituted cyclic metaborate ester having general formula (II) wherein n, R1 and R4, are defined as in formula (I); or a mixture of the acyclic compounds of formula (I) and the cyclic compounds of formula (II).

Cette invention concerne des composés de boroester renfermant du soufre qui constituent des additifs anti-usure utiles pour des compositions oléagineuses, dont des thioesthers de borate acyclique de formule générale (I) où R?1¿ représente un radical d'hydrocarbyle comprenant de 4 à 12 atomes de carbone, R?2¿ et R?3¿ représentent indépendamment -(OR?4¿)¿n?SR?1¿ et -(OR?4¿)¿n?SR?1¿OH; R?4¿ représente un radical d'hydrocarbyle ayant de 1 à 6 atomes de carbone; n est un entier compris entre 1 et 4; et 1 et m sont indépendamment 0, 1 ou 2; ou bien un ester métaborate cyclique substitué par thioalkyle de formule générale (II) où n, R?1¿ et R?4¿ sont définis comme dans la formule (I); ou bien un mélange des composés acycliques de formule (I) et des composés cycliques de formule (II).

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