Apparatus, process, and composition for in-situ generation...

C - Chemistry – Metallurgy – 01 – B

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C01B 6/00 (2006.01) B01J 7/00 (2006.01) B01J 8/06 (2006.01) C01B 6/06 (2006.01) C01B 6/24 (2006.01)

Patent

CA 2044347

ABSTRACT A system (100) for generating a gaseous polyhydridic Group IV-VI compound, comprising: a vessel (42) containing a solid precursor metal compound for the polyhydridic Group IV-VI compound; a source (14) of fluid-phase protonic activator compound reactive with the precursor compound to yield as reaction product (a) the polyhydridic compound and (b) a solid reaction product compound containing the metal moiety, e.g., a on-volatile metal salt; and means (16, 22) for flowing the activator compound from the source (14) thereof to the vessel containing the solid precursor compound. The precursor compound may suitably comprise a metal moiety such as lithium, sodium, magnesium, zinc, potassium, aluminum, and/or intermetallic complexes and alloys thereof. An appertaining method of generating such polyhydridic Group IV-VI compounds is likewise disclosed, together with a reaction vessel (400) for carrying out the contacting of precursor and activator therein.

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