Aqueous-dispersed polymer compositions containing cyanoalkyl...

C - Chemistry – Metallurgy – 08 – L

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C08L 25/02 (2006.01) C08F 212/04 (2006.01) C08F 236/10 (2006.01) C08L 33/02 (2006.01) C08L 33/14 (2006.01) C08L 47/00 (2006.01) D21H 19/58 (2006.01)

Patent

CA 1327417

ABSTRACT Aqueous-dispersed polymer compositions are prepared comprising polymerized therein (a) mono- vinylidene aromatic monomer (e.g., styrene), (b) acyclic conjugated diene monomer (e.g., butadiene), and (c) ethylenically unsaturated carboxylic acid monomer(s) (e.g. acrylic and or fumaric acid) and are further benefited by polymerizing therein (d) a cyanoalkyl ester of an ethylenically unsaturated carboxylic acid. The aqueous-dispersed polymers can also comprise polymerized therein an ethylenically unsaturated nitrile monomer such as acrylonitrile. The use of the cyanoalkyl ester, such as 2-cyanoethyl- methacrylate (2-CEMA), results in latex polymers with improved performance in paper coating formulations. In particular, paper coatings can be prepared which have improved performance (i.e., wet and dry pick resistance) in offset printing applications.

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