Aqueous phosphating composition and process for metal surfaces

C - Chemistry – Metallurgy – 23 – C

Patent

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C23C 22/07 (2006.01) C23C 22/12 (2006.01) C23C 22/17 (2006.01) C23C 22/18 (2006.01) C23C 22/36 (2006.01)

Patent

CA 2277967

An aqueous zinc phosphate conversion coating that contains 5 to 50 g/L of phosphate ions, 0.2 to 10 g/L of zinc ions, and 0.5 to 4.0 g/L as hydroxylamine of a hydroxylamine source, and also: (1) contains 0.01 to 5.0 g/L polycarboxylic acid or salt thereof and/or starch phosphate; or (2) has a zinc ions/phosphate ions weight ratio below 0.27 and a zinc ions concentration of at least 2.0 g/L forms high quality zinc phosphating coatings on metal surfaces even if the surfaces have not been previously conditioned by contact with a dispersion of colloidal titanium.

L'invention concerne une composition aqueuse de conversion à base de phosphate de zinc qui contient entre 5 et 50 g/L d'ions de phosphate, entre 0,2 et 10 g/L d'ions de zinc, et entre 0,5 et 4,0 g/L d'hydroxylamine d'une source d'hydroxylamine. Ladite composition aqueuse contient en outre (1) entre 0,001 et 5,0 g/L d'acide polycarboxylique ou le sel dudit acide et/ou un phosphate d'amidon; ou (2) un rapport en poids ions de zinc/ions de phosphate inférieur à 0,27 et une concentration d'ions de zinc d'au moins 2,0 g/L. La composition aqueuse donne des revêtements de phosphate-zinc de grande qualité sur des surfaces métalliques, même lorsque ces dernières ne sont pas préalablement traitées avec une dispersion de titane colloïdal.

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