Associative monomers and polymers

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 271/08 (2006.01) C08F 212/14 (2006.01) C08F 212/34 (2006.01) C08F 220/02 (2006.01) C08F 222/12 (2006.01) C08F 226/02 (2006.01) C08F 246/00 (2006.01) C08L 33/12 (2006.01) C08L 35/00 (2006.01) D06M 15/21 (2006.01) D06M 17/06 (2006.01)

Patent

CA 2127032

Novel mono- and multi-functional non-ionic urethane monomers are prepared from surfactants comprising poly(ethylene oxide) (butylene oxide) copolymers, preferably C1-C4 alkoxy-terminated, monohydric, ethylene oxide/butylene oxide block polymers and monoethylenically unsaturated aliphatic isocyanates. When polymerized with, e.g. acrylic acid or alkyl acrylates, these monomers provide copolymers exhibiting greatly enhanced thickening efficiency.

De nouveaux monomères d'uréthane non ioniques mono- et multifonctionnels sont préparés à partir de surfactants comprenant des copolymères de poly(oxyde d'éthylène) (oxyde de butylène), de préférence des polymères blocs d'oxyde d'éthylène-oxyde de butylène monohydrique à terminaison alcoxy en C1-C4, et des isocyanates aliphatiques à insaturation monoéthylénique. Lorsqu'ils sont polymérisés avec, par exemple, l'acide acrylique ou des acrylates d'alkyle, ces monomères donnent des copolymères présentant une efficacité d'épaississement grandement accrue.

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