Auto-oxidation and internal heating type reforming method...

C - Chemistry – Metallurgy – 01 – B

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Details

C01B 3/32 (2006.01) B01J 7/00 (2006.01) C01B 3/38 (2006.01) C01B 3/48 (2006.01)

Patent

CA 2571914

An auto-oxidation and internal heating type reforming reactor apparatus for hydrogen production for use in a process in which a small amount of an oxidizing catalyst is admixed with a mass of a reforming catalyst, a small amount of oxygen is admixed with a gaseous mixture of a hydrocarbon or an aliphatic alcohol with water vapor, and the gaseous mixture is fed into contact with the reforming catalyst in the mass to bring about a reforming reaction of the gaseous mixture therewith to produce hydrogen and an exothermal oxidization of a portion of the hydrocarbon or aliphatic alcohol to generate an amount of heat required to reform the gaseous mixture of the hydrocarbon or aliphatic alcohol with water vapor, wherein the apparatus comprises a reforming reaction catalyst loaded bed having a reforming reaction catalyst and a small amount of an oxidizing catalyst distributively admixed therewith and a thin layer of an oxidizing catalyst disposed at least one of behind and ahead of the reforming reaction catalyst loaded bed.

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