Azoalkane mixtures containing unsymmetrical azoalkanes and...

C - Chemistry – Metallurgy – 08 – F

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C08F 220/20 (2006.01) C07C 245/02 (2006.01) C07C 245/04 (2006.01) C08F 4/04 (2006.01) C08F 8/30 (2006.01) C08F 12/08 (2006.01) C08F 112/08 (2006.01) C08F 283/01 (2006.01) C08F 299/04 (2006.01)

Patent

CA 1249267

- i - Abstract Mixtures of azolakanes of varying thermal stabilities at least one of which is an unsymmetrical azoalkane (R-N=N-R'), are prepared by reacting 4 equivalents of a mixture of two or more primary alkyl, cycloalkyl or aralkylamines with 1 equivalent of sulfuryl chloride in an inert solvent and oxidizing the resulting mixture of sulfamide products with basic bleach. The unsymmetrical azoalkanes can be separated from the symmetrical azoalkanes by a variety of conventional techniques. The azoalkane mixtures are excellent polymerization initiators for vinyl monomers and curing agents for unsaturated polyester resins.

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