Ballast gas use in liquid phase oxidations

B - Operations – Transporting – 01 – J

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B01J 19/14 (2006.01) B01J 19/00 (2006.01) C07C 45/33 (2006.01)

Patent

CA 2286546

The amount of a ballast gas needed, to prevent combustion, deflagration, and/or detonations during a liquid phase reaction of molecular.oxygen and a flammable process liquid, is reduced by using a ballast gas other than nitrogen. The ballast gas is selected to have a boiling point lower than the boiling point of the flammable process liquid and selected to produce a higher limiting oxygen value (LOV) in a mixture with the flammable process liquid vapor and molecular oxygen than the LOV for the corresponding mixture substituting just nitrogen for the inerting gas.

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