Benzyloxy substituted aromatics and their use as fungicides...

C - Chemistry – Metallurgy – 07 – C

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C07C 69/736 (2006.01) A01N 37/38 (2006.01) A01N 37/42 (2006.01) A01N 37/50 (2006.01) A01N 43/06 (2006.01) A01N 43/34 (2006.01) A01N 43/48 (2006.01) A01N 43/647 (2006.01) A01N 43/72 (2006.01) C07C 69/738 (2006.01) C07C 69/757 (2006.01) C07C 205/35 (2006.01) C07C 235/34 (2006.01) C07C 235/78 (2006.01) C07C 251/48 (2006.01) C07C 255/46 (2006.01) C07C 255/54 (2006.01) C07C 255/56 (2006.01) C07C 317/22 (2006.01) C07C 323/16 (2006.01) C07C 323/22 (2006.01) C07D 207/337 (2006.01) C07D 213/30 (2006.01) C07D 213/50

Patent

CA 2242011

Compounds with fungicidal and insecticidal properties having formula (see fig. I) wherein A is N or CH; V is O or NH, m and n are the integers 0 and 1, provided that m + n is 0 or 1, X is independently selected from hydrogen, halo, (C1-C4)alkyl, and (C1-C4)alkoxy; R is independently selected from hydrogen, (C1-C12)alkyl, (C1-C12)alkoxy, halo(C1-C12)alkyl, (C2-C12)alkenyl, (C2-C12)alkynyl, (C1-C12)alkoxy(C1-C12)alkyl, (C3-C7)cycloalkyl, halo(C3-C7)cycloalkyl, (C3-C7)cycloalkyl(C1-C12)alkyl, (C3-C7)cycloalkyl(C2-C12)alkenyl, (C3-C7)cycloalkyl(C2-C12)alkynyl, (C1-C12)alkyl(C3- C7)cycloalkyl, (C1-C12)alkoxy(C3-C7)cycloalkyl, (C1-C12)alkoxy(C1-C12)alkyl(C3- C7)cycloalkyl, (C2-C12)alkenyl(C3-C7)cycloalkyl, (C2-C12)alkynyl(C3-C7)cycloalkyl, halo(C1-C12)alkyl(C3-C7)cycloalkyl, (C1-C12)alkoxy(C2-C12)alkenyl(C3-C7)cycloalkyl, (C1-C12)alkoxy(C2-C12)alkynyl(C3-C7)cycloalkyl, (C3-C7)cycloalkyl(C3-C7)cycloalkyl, (C1-C12)alkyl(C3-C7)cycloalkyl(C3-C7)cycloalkyl, (C2-C12)alkenyl(C3-C7)cycloalkyl(C3- C7)cycloalkyl, (C2-C12)alkynyl(C3-C7)cycloalkyl(C3-C7)cycloalkyl, (C3-C7)cycloalkyl(C1- C12)alkyl(C3-C7)cycloalkyl, (C3-C7)cycloalkyl(C2-C12)alkenyl(C3-C7)cycloalkyl, (C3-C7)cycloalkyl(C2-C12)alkynyl(C3-C7)cycloalkyl, (C3-C7)cycloalkyl(C1-C12)alkoxy(C3- C7)cycloalkyl, (C3-C7)cycloalkyl(C1-C12)alkoxy(C1-C12)alkyl(C3-C7)cycloalkyl, C7)cycloalkyl(C1-C12)alkoxy(C1-C12)alkenyl(C3-C7)cycloalkyl, (C3-C7)cycloalkyl(C1- C12)alkoxy(C1-C12)alkynyl(C3-C7)cycloalkyl, aryl, aralkyl, aryl(C3-C7)cycloalkyl, aryl(C3-C7)cycloalkyl(C3-C7)cycloalkyl, (C3-C7)cycloalkylaryl, aryl(C1-C4)alkyl(C3-C7)cycloalkyl, heterocyclic, aryl(C1-C4)alkylheterocyclic heterocyclic(C1-C4)alkyl, heterocyclic(C3- C7)cycloalkyl and R1, R2, R3 and R4 are independently selected from hydrogen, halogen, (C1-C12)alkyl, (C1-C12)alkoxy, halo(C1-C12)alkyl, (C2-C12)alkenyl, (C2-C12)alkynyl, (C3-C7)cycloalkyl, cyano, carboxy, (C1-C4)alkoxycarbonyl, aryl, and when taken together R2 and R3 form a (C3-C7)cycloalkyl ring, provided that when n=0 or 1 and m=0 R and R1 are not both hydrogen and when A is N and V is NH and n and m are both zero than R, R1, R2, R3 and R4 are other than 1 to 3 substituents independently selected from halogen and (C1-C4)alkyl.

Composés possédant des propriétés fongicides et insecticides, de formule (voir fig. I), où A est N ou CH; V est O ou NH, m et n sont les entiers 0 et 1, à la condition que m + n est 0 ou 1, X est choisi indépendamment parmi un hydrogène, un halogène, un groupe alkyle (C1-C4) et alcoxy (C1-C4); R est choisi indépendamment parmi un hydrogène, un groupe alkyle (C1-C12), alcoxy (C1-C12), haloalkyle (C1-C12), alcényle (C2-C12), alcynyle (C2-C12), alcoxy (C1-C12) alkyle (C1-C12), cycloalkyle (C3-C7), halocycloalkyle (C3-C7), cycloalkyle (C3-C7) alkyle (C1-C12), cycloalkyle (C3-C7) alcényle (C2-C12), cycloalkyle (C3-C7) alcynyle (C2-C12), alkyle (C1-C12) cycloalkyle (C3- C7), alcoxy (C1-C12) cycloalkyle (C3-C7), alcoxy (C1-C12) alkyle (C1-C12) cycloalkyle (C3- C7), alcényle (C2-C12) cycloalkyle (C3-C7), alcynyle (C2-C12) cycloalkyle (C3-C7), haloalkyle (C1-C12) cycloalkyle (C3-C7), alcoxy (C1-C12) alcényle (C2-C12) cycloalkyle (C3-C7), alcoxy (C1-C12) alcynyle (C2-C12) cycloalkyle (C3-C7), cycloalkyle (C3-C7) cycloalkyle (C3-C7), alkyle (C1-C12) cycloalkyle (C3-C7) cycloalkyle (C3-C7), alcényle (C2-C12) cycloalkyle (C3-C7) cycloalkyle (C3- C7), alcynyle (C2-C12) cycloalkyle (C3-C7) cycloalkyle (C3-C7), cycloalkyle (C3-C7) alkyle (C1- C12) cycloalkyle (C3-C7), cycloalkyle (C3-C7) alcényle (C2-C12) cycloalkyle (C3-C7), cycloalkyle (C3-C7) alcynyle (C2-C12) cycloalkyle (C3-C7), cycloalkyle (C3-C7) alcoxy (C1-C12) cycloalkyle (C3- C7), cycloalkyle (C3-C7) alcoxy (C1-C12) alkyle (C1-C12) cycloalkyle (C3-C7), cycloalkyle C3-C7) alcoxy (C1-C12) alcényle (C1-C12) cycloalkyle (C3-C7), cycloalkyle (C3-C7) alcoxy (C1- C12) alcynyle (C1-C12) cycloalkyle (C3-C7), aryle, aralkyle, arylcycloalkyle (C3-C7), arylcycloalkyle (C3-C7) cycloalkyle (C3-C7), cycloalkyle (C3-C7) aryle, arylalkyle (C1-C4) cycloalkyle (C3-C7), hétérocyclyle, arylalkyle (C1-C4) hétérocyclyle hétérocyclyle alkyle (C1-C4), hétérocyclyle cycloalkyle (C3- C7), R1, R2, R3 et R4 sont choisis indépendamment parmi un hydrogène, un halogène, un groupe alkyle (C1-C12), alcoxy (C1-C12), haloalkyle (C1-C12), alcényle (C2-C12), alcynyle (C2-C12), cycloalkyle (C3-C7), cyano, carboxy, alcoxy (C1-C4) carbonyle, aryle, et, R2 et R3 forment ensemble un cycle cycloalkyle (C3-C7), à la condition que, lorsque n = 0 ou 1 et m = 0 alors R et R1 ne peuvent être tous deux de l'hydrogène, et que, lorsque A est N, et V est NH, et n et m sont tous deux zéro, alors R, R1, R2, R3 et R4 sont autres que 1 à 3 substituants indépendamment choisis parmi un halogène et un alkyle (C1-C4).

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