C - Chemistry – Metallurgy – 08 – G
Patent
C - Chemistry, Metallurgy
08
G
252/124, 403/31
C08G 18/40 (2006.01) C08G 18/18 (2006.01) C08G 18/20 (2006.01) C08G 18/63 (2006.01)
Patent
CA 1040788
BETA-AMINO NITRILE CATALYSTS FOR POLYURETHANE PREPARATION ABSTRACT OF THE DISCLOSURE Cellular urethane polymers essentially free of the strong, objectionable amine odor characteristic of N-ethylmorpholine, are provided by effecting the poly- urethane forming reaction in the presence of beta-tert- amino nitriles. In view of their low residual odor and effectiveness in the catalysis of the water-isocyanate reaction, the beta-amino nitriles either alone or in combination with other tertiary amines, are used with particular advantage as direct replacements for N-ethyl- morpholine in the manufacture of water-blown flexible polyurethanes, both molded and free-rise, including high- resilience foam as well as foams stabilized with either organosilicone or silicon-free organic surfactants. Especially effective for the formation of flexible poly- ester foam stabilized with either type of surfactant are blends of the beta-amino nitrile catalyst such as, in particular, 3-(N,N-dimethylamino)propionitrile, with dimethylethanolamine or a bis[2-(N,N-dimethylamino)alkyl]- ether. S P E C I F I C A T I O N
197574
Rosemund Walter R.
Sandner Michael R.
Trecker David J.
Na
Union Carbide Corporation
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