Binuclear iridium(i) phosphine complexes and their use as...

C - Chemistry – Metallurgy – 07 – F

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C07F 17/02 (2006.01) C07B 53/00 (2006.01) C07C 209/60 (2006.01) C07C 211/45 (2006.01) C07C 231/18 (2006.01) C07C 303/38 (2006.01) C07C 311/08 (2006.01) C07C 311/21 (2006.01) C07D 209/08 (2006.01) C07F 15/00 (2006.01)

Patent

CA 2249958

The invention relates to binuclear iridium(I) phosphine complexes of the general formula Image in which X is fluorine, chlorine, bromine or iodine, and Image is in each case a chiral bidentate diphosphine ligand. The complexes are particularly suitable as catalysts for the inter- or intramolecular asymmetric hydroamination of prochiral olefins.

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