Binuclear, water soluble, rhodium complexes and their use as...

C - Chemistry – Metallurgy – 07 – C

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260/573.2, 260/4

C07C 47/02 (2006.01) C07C 45/50 (2006.01) C07C 47/228 (2006.01) C07F 15/00 (2006.01)

Patent

CA 1258677

PRECIS DE LA DIVULGATION: L'invention concerne de nouveaux complexes rhodiés, dinucléaires et hydrosolubles de formule générale (I): Image (I) Les symboles R et R', identiques ou différents, représentent chacun un radical hydrocarboné pouvant comporter un ou plusieurs substituants n'interférant pas avec les utilisations envisagées pour les complexes en cause, les symboles R et R' pouvant par ailleurs former ensemble un radical unique divalent. Le symbole TAPS représente un coordinat de triaryl- phosphine sulfonée. Le symbole L représente un coordinat de carbonyle (CO) ou un coordinat de triarylphosphine sul- fonée (TAPS). Ces complexes et/ou leurs solutions aqueuses peuvent être utilisés comme catalyseur d'hydroformylation.

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