Biological production of novel cyclohexadienediols

Details Biological production of novel cyclohexadienediols Biological production of novel cyclohexadienediols

C - Chemistry, Metallurgy

12

P

195/129, 402/362

C12P 17/02 (2006.01) C07C 39/18 (2006.01) C07C 49/825 (2006.01) C07D 317/20 (2006.01) C12P 7/02 (2006.01)

Patent

CA 2010773

44206 CAN 7A Abstract of the Disclosure Meta-hydroxyphenylacetylenes are produced from phenyl-substituted ketal or acetal precursors. Using biotransformation processes, these precursors serve as substrates that are converted to cis-dihydrodiol intermediates. The cis- dihydrodiols can be converted chemically to the corresponding meta-substituted compounds, e.g., meta-substituted phenols, and then to m-hydroxyphenylacetylene, which is an intermediate needed to produce acetylene-terminated resins. The biotransformation step employs arene-2,3-dioxygenase in intra- or extra- cellular form.

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