Bis- and tris(pyrazolyl)boratometal complex catalysts

C - Chemistry – Metallurgy – 07 – F

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Details

C07F 15/04 (2006.01) B01J 31/18 (2006.01) C07C 2/32 (2006.01) C07C 2/36 (2006.01) C07F 15/00 (2006.01) C08F 4/70 (2006.01) C08F 10/00 (2006.01) C08G 67/02 (2006.01)

Patent

CA 2240437

The invention relates to metal complexes of the general formula (I) or (I') which are suitable for the oligomerisation and polymerisation of olefinically unsaturated compounds, and for the copolymerisation thereof with carbon monoxide. In said formulae the substituents and indexes have the following meaning: M is a metal from the eighth subgroup of the periodic system of elements, E is an element from the fifth main group of the periodic system of elements, R1 to R11, R15 are substituents selected from the group comprising hydrogen, C1 to C30-carbon-organic rests and C3 to C30 silicon-organic rests, R12 to R14 are substituents selected from the group comprising C1 to C30 carbon-organic rests and C3 to C30 silicon-organic rests.

L'invention concerne des complexes métalliques de la formule générale (I) ou (I') qui peuvent être utilisés pour l'oligomérisation et la polymérisation de composés oléfiniquement insaturés, ainsi que pour leur copolymérisation avec du monoxyde de carbone. Dans lesdites formules, les substituants et les indices ont les significations suivantes: M représente un métal du huitième sous-groupe de la classification périodique des éléments, E représente un élément du cinquième groupe principal de la classification périodique des éléments, R<1> à R<11> et R<15> représentent des substituants choisis dans le groupe comprenant hydrogène, des restes organiques carbonés possédant 1 à 30 atomes de carbone et des restes organiques siliciés possédant 3 à 30 atomes de carbone, R<12> à R<14> représentent des substituants choisis dans le groupe comprenant des restes organiques carbonés possédant 1 à 30 atomes de carbone et des restes organiques siliciés possédant 3 à 30 atomes de carbone.

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