Bis- and tris-(u-oxo)-dimanganese complex salts, their...

C - Chemistry – Metallurgy – 07 – F

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C07F 13/00 (2006.01) B01J 31/18 (2006.01) C11D 3/39 (2006.01)

Patent

CA 2194339

Disclosed and claimed are bis- and tris-(µ-oxo)-dimanganese complex salts of the formula I [LMn(µ-O)a(µ-OAc)bMnL]XAy (I) where Ac is a C2-C8-acyl group, a is 1, 2 or 3, b is 0 when a is 2 or 3 or b is 2 when a is 1, x indicates the number of positive charges and is 2 or 3, A is an anion, y is the number of anions A required to balance the positive charges and L is a ligand, such as [N,N-bis(2-pyridyl(methyl)-N-methylamine or [N,N,N',N'-tetrakis(2-pyridylmethyl)-1,2-ethylenediamine, as well as catalysts for the oxidation of organic compounds and catalysts in oxidative bleaches including the salts.

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