Bis(tetrahydro-indenyl) metallocenes as...

C - Chemistry – Metallurgy – 07 – F

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C07F 17/00 (2006.01) C07C 13/465 (2006.01) C07F 7/08 (2006.01) C08F 10/00 (2006.01) C08F 4/659 (2006.01) C08F 10/02 (2006.01) C08F 10/06 (2006.01) C08F 110/02 (2006.01) C08F 110/06 (2006.01) C08F 210/06 (2006.01) C08F 210/16 (2006.01)

Patent

CA 2317588

A new class of bridged bis(tetrahydro-indenyl)metallocenes of formula (I), wherein M is Zr of Hf; X are monoanionic sigma ligands; (ZR1i)j is a divalent group bridging the two tetrahydro-indenyl residues; R2 and R3 are halogen, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl radicals; p is 0-3; i is 1 or 2; j is 1-4; m is 0-2; n is 0-8. Furthermore, catalysts systems for olefin polymerization containing them and the corresponding ligands are described.

L'invention concerne une nouvelle classe de bis(tétrahydro-indényl) métallocènes pontés représentés par la formule (I), dans laquelle M représente Zr ou Hf; X représente des ligands sigma à un seul anion; (ZR?1¿¿i?)¿j? représente un groupe divalent effectuant un pontage entre les deux résidus tétrahydro-indényle; R?2 ¿et R?3¿ représentent des radicaux alkyle, cycloalkyle, aryle, alkylaryle, arylalkyle ou halogène; p vaut 0-3; i vaut 1 ou 2; j vaut 1-4; m vaut 0-2; n vaut 0-8. L'invention concerne également des systèmes de catalyse destinés à une polymérisation d'oléfine contenant ces bis(tétrahydro-indényl) métallocènes et les ligands correspondants.

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