Black soluble conjugated polymers with highly transmissive...

C - Chemistry – Metallurgy – 08 – G

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C08G 61/12 (2006.01) C08L 65/00 (2006.01)

Patent

CA 2715013

A soluble donor- acceptor electrochromic polymer (DA-ECP) is prepared that absorbs light throughout at least the majority of the visible range and is essentially black to the human eye when in the neutral state, but is highly transmissive when electrochemically doped. The conjugated polymer has acceptor units separated by sequences of a plurality of donor units. The sequences can be monodispersed or polydispersed. The DA-ECP is prepared by the polycondensation of a plurality of at least one donor-acceptor oligomer (DA-oligomer) that has at least one internal acceptor repeating unit and at least one donor repeating unit on all termini of the oligomer, and optionally, a plurality of at least one donor monomer and/or donor oligomer.

Selon linvention, un polymère électrochromique donneur-accepteur soluble (DA-ECP) est préparé qui absorbe la lumière sur au moins la majorité du domaine visible et qui est essentiellement noir pour l'il humain lorsqu'il est dans l'état neutre, mais qui est hautement transmissif lorsqu'il est dopé électrochimiquement. Le polymère conjugué a des unités accepteurs séparées par des séquences d'une pluralité d'unités donneurs. Les séquences peuvent être monodispersées ou polydispersées. Le DA-ECP est préparé par la polycondensation d'une pluralité d'au moins un oligomère donneur-accepteur (DA-oligomère) qui a au moins une unité répétitive accepteur interne et au moins une unité répétitive donneur sur toutes les terminaisons de l'oligomère et, facultativement, une pluralité d'au moins un monomère donneur et/ou un oligomère donneur.

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