Blocky hydroxyethylcellulose, derivatives thereof, process...

C - Chemistry – Metallurgy – 08 – L

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C08L 1/28 (2006.01) C08B 11/08 (2006.01) C08B 11/20 (2006.01) C08B 15/00 (2006.01) C08L 1/08 (2006.01) C09D 101/28 (2006.01)

Patent

CA 2598068

This invention relates to non-uniformly substituted ('blocky') hydroxyethylcelluloses (HECs) and derivatives thereof that exhibit associative behavior in both neat solutions and in filled systems. The HECs and derivatives thereof exhibit unique and highly desirable rheology and are more efficient in thickening aqueous systems than prior art HEC products. These blocky HECs can be distinguished from prior art and commercial HEC products by having an unsubstituted anhydroglucose trimer ratio (U3R) greater than 0.21 and the hydroxethyl molar substitution greater than about 1.3 and less than about 5. This invention also relates to processes for making blocky HEC and uses thereof in functional systems.

L'invention concerne des hydroxyéthylcelluloses non uniformément substituées et des dérivés associés qui présentent un comportement associatif dans des solutions nettes et des systèmes remplis. Ces hydroxyéthylcelluloses et les dérivés associés ont une rhéologie unique et extrêmement souhaitable et sont plus efficaces dans des systèmes aqueux épaississants que des produits d'hydroxyéthylcelluloses de la technique antérieure. Ces hydroxyéthylcelluloses non uniformément substituées peuvent se distinguer de la technique antérieure et des produits commerciaux d'hydroxyéthylcelluloses, du fait qu'elles ont un rapport de trimère d'anhydroglucose non substituée supérieur à 0,21 et une substitution molaire d'hydroxéthyle supérieure à environ 1,3 et inférieure à environ 5. Cette invention a, également, trait à des processus de fabrication d'hydroxyéthylcelluloses non uniformément substituées et aux utilisations associées dans des systèmes fonctionnels.

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