Bonding compositions and shaped articles utilizing the...

C - Chemistry – Metallurgy – 08 – G

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154/140, 402/183

C08G 69/44 (2006.01) B32B 27/04 (2006.01) B32B 27/36 (2006.01)

Patent

CA 1218193

Bonding Compositions and Shaped Articles Utilizing the Bonding Compositions Abstract Bonding compositions for bonding polyesters or copolyesters to poly(vinyl alcohol) or copolymers thereof, the composition comprising a poly(esteramide) having an inherent viscosity of at least 0.8 dl/g, said poly(esteramide) containing repeating units from at least 70 mol percent of a dicarboxylic acid selected from pimelic, azelaic, sebacic acid or combi- nations thereof and optionally up to 30 mol percent of a second linear aliphatic dicarboxylic acid having at least four carbon atoms connected linearly between the two acid groups or an aromatic dicarboxylic acid; repeating units from 10 mol percent to 30 mol percent of a diamine selected from 1,6-hexanediamine, 1,4- cyclohexanebismethylamine or combinations thereof; and repeating units from 90 to 70 mol percent of a glycol selected from ethylene glycol, 1,4-butanediol, 1,4- cyclohexanedimethanol or combinations thereof. Also disclosed are shaped articles comprising a polyester polymer layer and a poly(vinyl alcohol) layer, the layers being bonded together with bonding compositions of this invention. It is preferred that the poly- (vinyl alcohol) layer be an ethylene-vinyl alcohol copolymer having an ethylene content of 30 to 50 mol percent. The shaped article may be an oriented film or an oriented bottle.

451953

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