Branched-chain monoalcohols and derivatives thereof,...

C - Chemistry – Metallurgy – 07 – C

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C07C 43/13 (2006.01) C07C 29/149 (2006.01) C07C 31/02 (2006.01) C07C 31/125 (2006.01) C07C 69/00 (2006.01) C08K 5/00 (2006.01) C08K 5/05 (2006.01) C08L 91/06 (2006.01) C10M 105/32 (2006.01)

Patent

CA 1142534

Abstract Novel branched-chain monoalcohols and derivatives thereof are disclosed. Such derivatives are selected from the group consis- ting of a) esters of aromatic, aliphatic or cycloallphatic acids having at least 2 carbon atoms and 1, 2 or 3 carboxyl groups; b) urethanes of aromatic, aliphatic or cycloaliphatic iso- cyanates; c) monoethers of polyalkylene oxide glycols having 2 to 50 alkylene oxide units each containing 2 or 3 carbon atoms and the alkyl- polyoxyalkylene sulfates derived therefrom; d) sulfates. The branched-chain monoalcohols are obtained by reduction of branched-chain monocarboxylic acids or esters thereof. Said acids are telomeric acids obtained by the free radical addition of I mole of acetic anhydride to at least three moles of hexene and/or higher ole- fins containing up to 30 or more carbon atoms (C30+) in the presence of a trivalent manganese compound. m e products of this invention are suitable for use in engine lubricating oils, lubricant compositions for polymers and wax compositions.

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