Branched surfactant manufacture

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 31/125 (2006.01) C07C 2/06 (2006.01) C07C 29/16 (2006.01) C07C 51/23 (2006.01) C07C 53/126 (2006.01) C07C 233/46 (2006.01) C07C 303/02 (2006.01) C07C 303/24 (2006.01) C07C 305/04 (2006.01) C07C 305/06 (2006.01) C07C 305/10 (2006.01) C07C 309/12 (2006.01) C11D 1/12 (2006.01) C11D 1/14 (2006.01) C11D 1/29 (2006.01) C11D 1/52 (2006.01) C11D 1/65 (2006.01) C11D 1/72 (2006.01) C11D 1/722 (2006.01) C11D 1/835 (2006.01) C11D 3/08 (2006.01) C11D 3/12 (2006.01) C11D 3/18 (2006.01) C11D 1/62 (2006.01)

Patent

CA 2252435

Alpha-olefins are dimerised to form vinylidene olefins, which are then isomerised and reacted with CO/H2 under OXO conditions or reacted directly with CO/H2 under OXO conditions to give mid- to near-mid chain branched alcohols. These branched-chain alcohols are feedstocks for the production of alkyl sulphate, alkyl ethoxy sulphate, and alkyl carboxylate surfactants and other surfactants.

Des alpha-oléfines sont dimérisées afin d'obtenir des oléfines de vinylidène, lesquelles sont ensuite isomérisées et soumises à une réaction avec CO/H2 dans des conditions OXO, ou à une réaction directe avec CO/H2 dans des conditions OXO, de manière à produire des alcools ramifiés en milieu ou près du milieu de chaîne. Ces alcools à chaîne ramifiée représentent des charges pour la fabrication de tensioactifs à base de sulfate d'alkyle, de sulfate d'éthoxyalkyle et de carboxylate d'alkyle, ainsi que d'autres tensioactifs.

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