Bridged bi-aromatic ligands, complexes, catalysts and...

C - Chemistry – Metallurgy – 07 – F

Patent

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C07F 5/00 (2006.01) C07D 209/86 (2006.01) C07F 7/00 (2006.01) C07F 9/00 (2006.01) C07F 9/50 (2006.01) C07F 11/00 (2006.01) C08F 110/06 (2006.01) C08F 210/02 (2006.01) C08F 210/16 (2006.01)

Patent

CA 2483192

New ligands, compositions, metal-ligand complexes and arrays with bridged bis- aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.

L'invention concerne des ligands, des compositions, des complexes métal-ligand et des réseaux de ligands biaromatiques pontés catalysant la polymérisation de monomères en polymères. Ces catalyseurs à centre métallique possèdent des caractéristiques élevées de performance, y comprise une incorporation plus importante de comonomère dans des copolymères éthylène/oléfine, où ces oléfines sont, par exemple, du 1-octène, du propylène ou du styrène. Ces catalyseurs permettent aussi de polymériser du propylène en polypropylène isotactique.

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