Bulk polymerization of vinyl chloride

C - Chemistry – Metallurgy – 08 – F

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402/304, 402/396

C08F 14/06 (2006.01) C08F 2/00 (2006.01)

Patent

CA 1085994

ABSTRACT OF THE DISCLOSURE Vinyl chloride monomer or a mixture thereof with a copolymerizable monomer or monomers is bulk-polymerized so that the deposition of polymer scale on the inner walls of the polymerization vessel and other surfaces in contact with the monomer or monomers can be greatly reduced by coating them with phosphoric esters, polyphosphoric esters or their alkali metal salts before the polymerization is commenced. Clean-up operations following each polymerization run are much simplified.

237921

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