Butenol-triazolyl derivatives, their manufacture and use as...

Details Butenol-triazolyl derivatives, their manufacture and use as... Butenol-triazolyl derivatives, their manufacture and use as...

C - Chemistry, Metallurgy

07

D

C07D 249/08 (2006.01) A01N 43/653 (2006.01) C07C 33/50 (2006.01) C07C 43/196 (2006.01) C07C 43/23 (2006.01) C07C 45/68 (2006.01) C07C 45/75 (2006.01) C07C 49/527 (2006.01) C07C 49/567 (2006.01) C07C 205/16 (2006.01) C07C 205/45 (2006.01) C07D 303/02 (2006.01) C07D 303/08 (2006.01) C07D 521/00 (2006.01)

Patent

CA 2171754

HYdroxyethyl-azolYl derivatiVes A b s t r a c t New hydroxyethyl-azolyl derivatives of the formula Image (I), in which X represents hydrogen, halogen, alkyl having 1 to 4 carbon atoms or alkoxy having 1 to 4 carbon atoms, Z represents halogen, alkyl having 1 to 4 carbon atoms, halogenoalkyl having 1 to 4 carbon atoms and 1 to 5 halogen atoms, alkoxy having 1 to 4 carbon atoms, halogenoalkoxy having 1 to 4 carbon atoms and 1 to 5 halogen atoms, nitro, or phenyl which is optionally monosubstituted to trisubstituted by identical or different halogen atoms, and m represents the numbers 0, 1, 2 or 3, and their acid addition salts and metal salt complexes, - 1 - a process for the preparation of the new substances, and their use as microbicides in plant protection and in the protection of materials. New butenol derivatives of the formula Image (II), new oxiranes of the formula Image (III) and new ketones of the formula Image (X), - 2 - process for the preparation of these substances and their use as intermediates for the synthesis of compounds of the formula (I). - 3 -

L'invention concerne de nouveaux dérivés de buténol-trizolyle de la formule (I), dans laquelle X désigne hydrogène, halogène, alkyle ayant entre 1 et 4 atomes de carbones, ou alcoxy entre 1 et 4 atomes de carbone, Z désigne halogène, alkyle ayant entre 1 et 4 atomes de carbone, halogénure d'alcoyle ayant entre 1 et 4 atomes de carbone et entre 1 et 5 atomes d'halogène, alcoxy ayant entre 1 et 4 atomes de carbone, halogénure d'alcoxy ayant entre 1 et 4 atomes de carbone et entre 1 et 5 atomes d'halogène, nitro ou phényle éventuellement substitué entre une et trois fois par halogène, de manière identique ou différente et m vaut 0, 1, 2 ou 3. L'invention concerne également leurs sels d'addition d'acide et leurs complexes de sels métalliques, un procédé permettant de préparer les nouvelles substances et leur utilisation comme microbicides dans la protection des végétaux et des matériaux. L'invention concerne par ailleurs de nouveaux dérivés de buténol de la formule (II), de nouveaux oxirannes de la formule (III), de nouvelles cétones de la formule (X), des procédés de préparation de ces substances et leur utilisation comme produits intermédiaires pour réaliser la synthèse des composés de la formule (I).

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